The Journal of Organic Chemistry

Chemistry of Nitrosyl Fluoride. II. Reactions of Nitrosyl Fluoride with Fluoroölefins1

S Andreades

文献索引：Andreades,S. Journal of Organic Chemistry, 1962 , vol. 27, p. 4163 - 4170

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被引用次数: 40

摘要

Reactions of nitrosyl fluoride with tetrafluoroethylene, hexafluoropropene, octafluoroisobutene, and octafluoro-2-buterie to give oxazetidines, nitroso compounds, and/or azaalkenes are described. A rationalization of relative reactivities of ant1 direction of addition to fluoroolefins is presented. Detailed studies of the nitrosyl fluoride- hexafluoropropene reaction led to a new synthesis of perfluoroazaalkenes. Thermal ...