Reactions of nitrosyl fluoride with tetrafluoroethylene, hexafluoropropene, octafluoroisobutene, and octafluoro-2-buterie to give oxazetidines, nitroso compounds, and/or azaalkenes are described. A rationalization of relative reactivities of ant1 direction of addition to fluoroolefins is presented. Detailed studies of the nitrosyl fluoride- hexafluoropropene reaction led to a new synthesis of perfluoroazaalkenes. Thermal ...
![[1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-yl] nitrite Structure](https://image.chemsrc.com/caspic/289/677-88-3.png)
