One pot catalytic NO 2 reduction, ring hydrogenation, and N-alkylation from nitroarenes to generate alicyclic amines using Ru/C-NaNO 2

…, V Mishra, JK Cho, BJ Kim, HS Kim, YW Suh…

文献索引：Oh, Seung Geun; Mishra, Vivek; Cho, Jin Ku; Kim, Baek-Jin; Kim, Hoon Sik; Suh, Young-Woong; Lee, Hyunjoo; Park, Ho Seok; Kim, Yong Jin Catalysis Communications, 2014 , vol. 43, p. 79 - 83

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被引用次数: 11

摘要

Abstract A report to produce alicyclic amines and subsequent N-alkylation with alcohols using Ru/C-NaNO 2 catalyzed facile transformation of nitrobenzene was investigated. Effects of solvent, temperature, pressure, reaction time, and molar-ratio of substrate/catalyst on product composition were also studied. These mechanistic studies explain that nitrobenzene undergoes hydrogenation reaction in the following order;–NO 2 reduction to ...