Journal of Organic Chemistry 2011-09-02

Synthesis of the scalarane sesterterpenoid 16-deacetoxy-12-epi-scalarafuranacetate.

Xi-Bo Chen, Qian-Jia Yuan, Jing Wang, Si-Kai Hua, Jiangmeng Ren, Bu-Bing Zeng

文献索引：J. Org. Chem. 76(17) , 7216-21, (2011)

摘要

The marine natural product 16-deacetoxy-12-epi-scalarafuranacetate, isolated from Spongua officinalis , was synthesized in 18 linear steps, starting from (-)-sclareol, with high stereoselectivity and an overall yield of 6.1%. The intermediate 16-deacetoxy-12-epi-scalarafuran could be easily transformed into a series of natural scalarane sesterterpenoids in a few steps.

结构式	名称/CAS号	分子式	全部文献
	香紫苏醇 CAS:515-03-7	C₂₀H₃₆O₂

Parallel dual secondary column-dual detection: a further way...
2014-09-19
[J. Chromatogr. A. 1360 , 264-74, (2014)]

Labdane diterpenoids from Salvia reuterana.
2014-12-01
[Phytochemistry 108 , 264-9, (2014)]

Isolation, chemical, and biotransformation routes of labdane...
2011-08-10
[Chem. Rev. 111(8) , 4418-52, (2011)]

Bioactive constituents of Salvia chrysophylla Stapf.
2013-03-01
[Nat. Prod. Res. 27(4-5) , 438-47, (2013)]

Hemisynthesis of new labdane derivatives from (-)-sclareol.
2006-08-01
[Nat. Prod. Res. 20(10) , 887-95, (2006)]

Synthesis of the scalarane sesterterpenoid 16-deacetoxy-12-epi-scalarafuranacetate.

摘要

相关化合物