Condensations at the Methyl Groups of N-Acetylbenzamide and Diacetylimide by Means of Potassium Amide in Liquid Ammonia

SD Work, DR Bryant, CR Hauser

文献索引：Work,S.D. et al. Journal of the American Chemical Society, 1964 , vol. 86, p. 872 - 876

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被引用次数: 7

摘要

Condensations at the methyl groups of S-acetylbenzamide and diacetylimide were accomplished through their dipotassio salts IIa-b, which were prepared by means of two molecular equivalents of potassium amide in liquid ammonia. The condensations involved benzylation, benzoylation, and an aldol-type condensation with benzyl chloride, meth) 1 benzoate, and benzophenone, respectively. The benzplations of IIa-b were realized in ...