Selective Reduction of Esters to Aldehydes under the Catalysis of Well??Defined NHC–Iron Complexes

…, LC Misal Castro, J Zheng, T Roisnel…

文献索引：Li, Haoquan; Misal Castro, Luis C.; Zheng, Jianxia; Roisnel, Thierry; Dorcet, Vincent; Sortais, Jean-Baptiste; Darcel, Christophe Angewandte Chemie - International Edition, 2013 , vol. 52, # 31 p. 8045 - 8049 Angew. Chem., 2013 , vol. 125, # 31 p. 8203 - 8207

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被引用次数: 63

摘要

Aldehydes are important building blocks used as reactive intermediates in organic and total synthesis. Their preparation from primary alcohols through oxidative pathways or from carboxylic derivatives by reductive methods is still challenging, as they are usually more reactive than the starting materials towards both oxidation and reduction, and this higher reactivity often leads to chemoselectivity issues.[1] For the specific reduction of esters to ...