Macrocyclic Enzyme Model System. Kinetic Activity of [20] Paracyclophane Bearing 1, 4-Dihydronicotinamide and 2-Pyridinecarboxylic Acid Moieties as Effected by …

Y Murakami, Y Aoyama, J Kikuchi

文献索引：Murakami, Yukito; Aoyama, Yasuhiro; Kikuchi, Jun-ichi Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 9 p. 2898 - 2901

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被引用次数: 11

摘要

As regards the effect of zinc (II) ion on the reduction of hexachloroacetone, the kinetic activity of a [20] paracyclophane (PCP) bearing 1, 4-dihydronicotinamide (HNA) and 2- pyridinecarboxylic acid (Py) moieties, HNA–PCP–Py, has been investigated as an alcohol dehydrogenase model in reference to that of PCP–HNA in the light of their metal- coordination behavior. The reduction ability of PCP–HNA was significantly lowered as it ...