Journal of fluorine chemistry

On the reaction of perfluoro-aza-propene with oxygen difluoride and fluorination of bis (trifluoromethyl)-hydroxylamine

R Minkwitz, S Reinemann, R Ludwig

文献索引：Minkwitz, Rolf; Reinemann, Stefan; Ludwig, Ralf Journal of Fluorine Chemistry, 1999 , vol. 99, # 2 p. 145 - 149

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被引用次数: 4

摘要

The reactions of perfluoro-aza-propene CF3NCF2 with an excess of oxygen difluoride OF2 and the fluorination of bis (trifluoromethyl)-hydroxylamine (CF3) 2NOH are discussed. Additionally, we present density functional calculations (B3LYP/6-31G*) on bis (trifluoromethyl)-hypofluorite (CF3) 2NOF, which clearly show that this molecule is a model substance for the discussion of negative hyperconjugation.