Perfluorooctylation of aromatic compounds with perfluoroazooctane upon 185 nm irradiation in a two-phase system

T Nakamura, Y Koga

文献索引：Nakamura, Takako; Koga, Yoshinori Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 3 p. 659 - 662

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被引用次数: 14

摘要

An efficient method for the preparation of perfluorooctylated aromatic and heteroaromatic compounds has been developed using photolysis of perfluoroazooctane (E)-1 upon 185 nm irradiation. The use of a two-phase system made up of a perfluorohexane solution of (E)-1 and a suitable aromatic compound has proved efficient for this reaction. The photolytic mechanism of (E)-1 upon 185 nm irradiation has also been investigated on the basis of ...