Journal of Fluorine Chemistry

Direct perfluoroalkylation of functionalized benzenes with perfluoroalkyl halides and copper bronze

T Fuchikami, I Ojima

文献索引：Fuchikami, Takamasa; Ojima, Iwao Journal of Fluorine Chemistry, 1983 , vol. 22, p. 541 - 556

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被引用次数: 34

摘要

Abstract Perfluoroalkyl halides were found to react with functionalized benzenes in the presence of copper bronze to give the corresponding perfluoroalkylated products directly in moderate to good yields. The reaction may involve 'active species' other than perfluoroalkylcopper species. Synthetic utility and possible mechanisms of the present one- step reaction are discussed.