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Journal of the American Chemical Society

The Preparation of Amines by Catalytic Hydrogenation of Derivatives of Aldehydes and Ketones

CF Winans, H Adkins

文献索引:Winans; Adkins Journal of the American Chemical Society, 1933 , vol. 55, p. 2051,2056

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被引用次数: 25

摘要

Summary The action of aqueous hydrochloric acid on divinylacetylene yields a dihydrochloride. The compound is oxidized by permanganate with the formation of acetic acid and chloroacetic acid, and this fact together with a consideration of the probable mechanism of its formation, indicates that it has the structure dichloro-1, 3-hexadiene-2, 4 and that it results from two successive acts of 1, 4 addition. When treated with sodium ...

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