Journal of Fluorine Chemistry

A new entry for the oxidation of fluoroalkyl-substituted methanol derivatives: Scope and limitation of the organoiodine (V) reagent-catalyzed oxidation

Y Tanaka, T Ishihara, T Konno

文献索引：Tanaka, Yusuke; Ishihara, Takashi; Konno, Tsutomu Journal of Fluorine Chemistry, 2012 , vol. 137, p. 99 - 104

被引用次数: 17

摘要

Oxidation of various fluoroalkyl-substituted methanol derivatives under the influence of a catalytic amount of sodium 2-iodobenzenesulfonate and Oxone® in CH3CN or CH3NO2 was investigated in detail. The efficiency of the newly developed oxidation was also evaluated by comparison to other oxidations, such as Dess–Martin, PDC, and Swern oxidation.

340-04-5

α-(三氟甲基)苄醇

~95%

434-45-7

α,α,α-三氟苯乙酮

~47%

~90%

~81%

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