Tetrahedron

N 1, N 10-Ethylene-bridged high-potential flavins: synthesis, characterization, and reactivity

WS Li, N Zhang, LM Sayre

文献索引：Li, Wen-Shan; Zhang, Nanjing; Sayre, Lawrence M. Tetrahedron, 2001 , vol. 57, # 21 p. 4507 - 4522

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被引用次数: 31

摘要

N1, N10-Ethyleneisoalloxazinium chloride and its 8-Cl-, 7-CF3-, and 3-CH3-7-CF3- substituted analogs were synthesized for the purpose of exhibiting thermal reactivity with organic substrates. The new flavins were characterized spectroscopically and electrochemically, and were found to react with amines, thiols, and phenylhydrazine, the latter case exhibiting catalytic aerobic recycling. Reactions of aliphatic benzylic and ...