Stereoselective debromination and selective reduction of vic-dibromides with nickel boride

…, BM Kandpal, G Kukreja, P Sharma

文献索引：Khurana, Jitender M.; Kandpal, Bhaskar M.; Kukreja, Gagan; Sharma, Purnima Canadian Journal of Chemistry, 2006 , vol. 84, # 8 p. 1019 - 1023

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被引用次数: 12

摘要

A simple procedure is reported for the stereoselective debromination of vic-dibromides with nickel boride at ambient temperature. Debromination with concomitant reduction of vic- dibromides to give dihydro products in a one-pot reaction is also reported. α, β- Dibromoketones can also be converted to their corresponding alcohols. Key words: debromination, vic-dibromides, stereoselective, reduction, E-alkenes.

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