Degradation of the Side Chain of (−)??Sclareol: A Very Short Synthesis of nor??Ambreinolide and Ambrox

…, EJ Alvarez??Manzaneda, R Chahboun…

文献索引：Barrero; Alvarez-Manzaneda; Chahboun; Arteaga Synthetic Communications, 2004 , vol. 34, # 19 p. 3631 - 3643

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被引用次数: 14

摘要

The synthesis of nor??Ambreinolide (8) from (??)??sclareol (1) was carried out by treatment with KMnO 4 ??Ac 2 O and further alkaline hydrolysis. 8 was directly transformed into (??)??ambrox (11) by reduction with metal borohydride in the presence of Lewis acids. ... The synthesis of nor??Ambreinolide (8) from (??)??sclareol (1) was carried out by treatment with KMnO 4 ??Ac 2 O and further alkaline hydrolysis. 8 was directly transformed into (??)??ambrox (11) by ...