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Betylates. 3. Preparative nucleophilic substitution by way of [2]-,[3]-, and [4] betylates. Stoichiometric phase transfer and substrate-reagent ion-pair (SRIP) reactions of …

JF King, SM Loosmore, M Aslam, JD Lock…

文献索引:King,J.F.; Loosmore,S.M.; Aslam,M. Journal of the American Chemical Society, 1982 , vol. 104, p. 7108

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被引用次数: 35

摘要

Abstract: The preparation of [2]-,[3]-, and [4] betylates ((trialky1ammonio) alkanesulfonates) and the corresponding norbetylates ((dia1kylammonio) alkanesulfonates) is described, and their use as intermediates in the transformation of the hydroxyl group of primary and secondary alcohols is illustrated by examples involving 36 different nucleophiles and 10 different alkyl groups; for a number of products these procedures provide what appears to ...

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