Syntheses and electronic structures of decamethylmetallocenes

JL Robbins, N Edelstein, B Spencer…

文献索引：Robbins,J.L.; Edelstein,N.; Spencer,B. Journal of the American Chemical Society, 1982 , vol. 104, p. 1882

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被引用次数: 333

摘要

Absbact: The syntheses of the (Me5Cp) 2M (M= Mg, V, Cr, Co, and Ni) and [(Me5Cp) 2M] PF6 (M= Cr, Co, and Ni) compounds are described. In addition, a preparative route to a novel, dicationic decamethylmetallocene,[(Me5Cp), Ni](PF,),, is reported. Physical measurements indicate that all the above compounds are Dsd or D,, decamethylmetallocenes with low-spin electronic configurations. The ...