Study of radical decarboxylation toward functionalization of naphthoquinones

…, C Chalumeau, J Dessolin, M Laguerre

文献索引：Commandeur, Claude; Chalumeau, Celine; Dessolin, Jean; Laguerre, Michel European Journal of Organic Chemistry, 2007 , # 18 p. 3045 - 3052

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被引用次数: 7

摘要

Abstract In order to obtain functionalized naphthoquinones, a systematic study of the Kochi– Anderson procedure for the alkylation of quinones is presented. While linear amino acids of different lengths were good substrates for this decarboxylation procedure, chiral α-amino acids were unsuccessful substrates. The best reaction conditions were evaluated with β- alanine and then applied to a series of carboxylic acids to obtain chemical diversity on the ...