Synthetic Communications®

Nickel boride–mediated cleavage of 1, 3-dithiolanes: a convenient approach to reductive desulfurization

JM Khurana, D Magoo

文献索引：Khurana, Jitender M.; Magoo, Devanshi Synthetic Communications, 2010 , vol. 40, # 19 p. 2908 - 2913

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被引用次数: 12

摘要

1, 3-Dithiolanes are rapidly cleaved by nickel boride, generating corresponding hydrocarbons in excellent yields. The hydrogenolysis is rapid at room temperature and does not require protection from the atmosphere. Mild reaction conditions, simple workup, and good yields of pure products are some of the major advantages of the procedure.