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Journal of fluorine chemistry

Synthesis and polymerization of novel fluorinated morpholino acrylates and methacrylates

B Guyot, B Améduri, B Boutevin

文献索引:Guyot, Bernard; Ameduri, Bruno; Boutevin, Bernard Journal of Fluorine Chemistry, 1995 , vol. 74, # 2 p. 233 - 240

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被引用次数: 26

摘要

The synthesis of four fluorinated acrylates and methacrylates bearing a morpholino group in the lateral chain was achieved in four steps in very high yield: the radical addition of perfluoroalkyl iodides on to allyl acetate followed by an alkaline cyclization led to fluorinated epoxides. These compounds reacted with an excess of morpholine and yielded morpholinofluorinated alcohols that, condensed with acrylic or methacrylic anhydride, ...