Journal of fluorine chemistry

Synthesis and polymerization of novel fluorinated morpholino acrylates and methacrylates

B Guyot, B Améduri, B Boutevin

Index: Guyot, Bernard; Ameduri, Bruno; Boutevin, Bernard Journal of Fluorine Chemistry, 1995 , vol. 74, # 2 p. 233 - 240

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Citation Number: 26

Abstract

The synthesis of four fluorinated acrylates and methacrylates bearing a morpholino group in the lateral chain was achieved in four steps in very high yield: the radical addition of perfluoroalkyl iodides on to allyl acetate followed by an alkaline cyclization led to fluorinated epoxides. These compounds reacted with an excess of morpholine and yielded morpholinofluorinated alcohols that, condensed with acrylic or methacrylic anhydride, ...