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Chemical Communications 2013-02-28

Rapid one-pot propargylamine synthesis by plasmon mediated catalysis with gold nanoparticles on ZnO under ambient conditions.

María González-Béjar, Kate Peters, Geniece L Hallett-Tapley, Michel Grenier, Juan C Scaiano

文献索引:Chem. Commun. (Camb.) 49(17) , 1732-4, (2013)

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摘要

Surface plasmon excitation of gold nanoparticles on ZnO in the presence of an aldehyde, an amine and phenylacetylene led to rapid and selective formation of propargylamines with good yields (50-95%) at room temperature. Plasmon mediated catalysis is the best available route for this ternary coupling.

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