The synthesis and properties of dimethylgallane: structure of the dimer Me 2 Ga (µ-H) 2 GaMe 2 in the gas phase as determined by electron diffraction

…, MJ Goode, DWH Rankin, HE Robertson

文献索引：Baxter, Paul L.; Downs, Anthony J.; Goode, Michael J.; Rankin, David W. H.; Robertson, Heather E. Journal of the Chemical Society, Chemical Communications, 1986 , # 10 p. 805 - 806

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摘要

Dimethylgallane, best synthesised by the reaction between trimethylgallane and sodium tetrahydrogallate, has been characterised by its spectroscopic and chemical properties; electron diffraction has established the structure of the dimer Me2Ga (µ-H) 2GaMe2, the predominant vapour species at low pressure.