Organic Letters 2009-05-07

Inter- and intramolecular photochemical reactions of fleroxacin.

Elisa Fasani, Sandra Monti, Ilse Manet, Fedele Tilocca, Luca Pretali, Mariella Mella, Angelo Albini

文献索引：Org. Lett. 11(9) , 1875-8, (2009)

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摘要

In the cation formed by photoinduced C-F bond cleavage in fleroxacin, intramolecular reaction with the N-ethyl chain is prevented by the electron-withdrawing effect of fluorine and intermolecular attack by nucleophiles is facilitated.