Chemical Communications 2013-09-14

PHIP-label: parahydrogen-induced polarization in propargylglycine-containing synthetic oligopeptides.

Marco Körner, Grit Sauer, Andreas Heil, Daichi Nasu, Martin Empting, Daniel Tietze, Stephan Voigt, Heiko Weidler, Torsten Gutmann, Olga Avrutina, Harald Kolmar, Tomasz Ratajczyk, Gerd Buntkowsky

文献索引：Chem. Commun. (Camb.) 49(71) , 7839-41, (2013)

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摘要

The unsaturated side chain of l-propargylglycine (Pra) was used to study parahydrogen-induced polarization (PHIP) in synthetic oligopeptides. For the first time PHIP-induced NMR signal enhancement was demonstrated using model peptides bearing various functional side chains.