Roles of surface protonation on the photodynamic, catalytic, and other properties of polyoxometalates probed by the photochemical functionalization of alkanes. …

…, M Kadkhodayan, M Pasquali, CL Hill

文献索引：Renneke, Roman F.; Kadkhodayan, Miryam; Pasquali, Marzia; Hill, Craig L. Journal of the American Chemical Society, 1991 , vol. 113, # 22 p. 8357 - 8367

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被引用次数: 62

摘要

Abstract: This paper further addresses the photodynamic and redox properties of polyoxometalates and the legitimacy of these compounds as discrete molecular representations for semiconductor metal oxides. The effect of protonation on redox, photochemical, catalytic, and other basic properties of a representative polyoxometalate, decatungstate (Wlo032e), in aprotic media has been examined in detail. Protonation ...