Roles of surface protonation on the photodynamic, catalytic, and other properties of polyoxometalates probed by the photochemical functionalization of alkanes. …

…, M Kadkhodayan, M Pasquali, CL Hill

Index: Renneke, Roman F.; Kadkhodayan, Miryam; Pasquali, Marzia; Hill, Craig L. Journal of the American Chemical Society, 1991 , vol. 113, # 22 p. 8357 - 8367

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Citation Number: 62

Abstract

Abstract: This paper further addresses the photodynamic and redox properties of polyoxometalates and the legitimacy of these compounds as discrete molecular representations for semiconductor metal oxides. The effect of protonation on redox, photochemical, catalytic, and other basic properties of a representative polyoxometalate, decatungstate (Wlo032e), in aprotic media has been examined in detail. Protonation ...