Lipase behavior in the stereoselective transesterification of zingerol-like derivatives and related biphenyls

C Sanfilippo, A Patti, MA Dettori, D Fabbri…

文献索引：Sanfilippo, Claudia; Patti, Angela; Dettori, Maria Antonietta; Fabbri, Davide; Delogu, Giovanna Journal of Molecular Catalysis B: Enzymatic, 2013 , vol. 90, p. 107 - 113

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被引用次数: 1

摘要

Using a highly stereoselective enzymatic procedure based on the irreversible transesterification of alcoholic functions in organic solvent, both enantiomers of zingerol and dehydrozingerol O-methyl derivatives 1 and 2 were obtained in high optical purity. The biocatalytic method was then extended to the corresponding biphenyl derivatives 5–8 for which an one-pot resolution/desymmetrization was carried out on the whole racemic/meso ...