Microwave??Assisted One??Step Synthesis of Acetophenones via Palladium??Catalyzed Regioselective Arylation of Vinyloxytrimethylsilane

W Qian, L Zhang, H Sun, H Jiang…

文献索引：Qian, Wangke; Zhang, Lei; Sun, Haifeng; Jiang, Hualiang; Liu, Hong Advanced Synthesis and Catalysis, 2012 , vol. 354, # 17 p. 3231 - 3236

全文：HTML全文

被引用次数: 6

摘要

Abstract The regiochemistry of the palladium-mediated arylation (Heck arylation) of enol ethers is sensitive to the structure of the enol ether, the arylating agent and the catalytic system. In this study, an effective and practical method was successfully developed for the synthesis of acetophenones with high regioselectivity under palladium-catalyzed conditions. A variety of acetophenones was readily prepared from aryl iodides in good to excellent ...