Chemoselective Hydrogenation Catalyzed by Pd on Spherical Carbon

…, A Tsubone, S Mibayashi, T Sakata, Y Sawama…

文献索引：Esaki, Hiroyoshi; Hattori, Tomohiro; Tsubone, Aya; Mibayashi, Satoko; Sakata, Takao; Sawama, Yoshinari; Monguchi, Yasunari; Yasuda, Hidehiro; Nosaka, Kazuto; Sajiki, Hironao ChemCatChem, 2013 , vol. 5, # 12 p. 3629 - 3635

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被引用次数: 6

摘要

Abstract We have developed a highly chemoselective hydrogenation method using a novel palladium catalyst supported on spherical carbon (0.5% Pd/SC). The 0.5% Pd/SC exhibited a novel catalytic activity and could achieve the chemoselective hydrogenation of alkynes, alkenes, azides, nitro groups, and aliphatic O-tert-butyldimethylsilyl (TBS) ethers without hydrogenolysis of benzyl esters, benzyl ethers, nitriles, aromatic ketones, N- ...