Tetrahedron letters

Solvent-induced hydrogen tunnelling in ascorbate proton-coupled electron transfers

A Karković, CJ Brala, V Pilepić, S Uršić

文献索引：Karkovic, Ana; Brala, Cvijeta Jakobusic; Pilepic, Viktor; Ursic, Stanko Tetrahedron Letters, 2011 , vol. 52, # 15 p. 1757 - 1761

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被引用次数: 7

摘要

Quantum-mechanical hydrogen tunnelling is of remarkable significance for chemistry and biochemistry. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18 and 19 The role of hydrogen tunnelling in such fundamental chemical reactions as hydrogen transfers is well documented 3, 4, 17, 18 and 19 and enzymatic C–H activation has been shown to take place via tunnelling. 2, 3, 4, 5, 6, 7, 8, 9, 10, 13, 14 and 16 Many non-enzymatic H-transfer ...