Organic Letters 2005-03-03

PS-COD and PS-9-BBN: polymer-supported reagents for solution-phase parallel synthesis.

Jefferson D Revell, Barbara Dörner, Peter D White, A Ganesan

文献索引：Org. Lett. 7(5) , 831-3, (2005)

全文：HTML全文

摘要

1,5-Cyclooctadiene was deprotonated under LICKOR conditions and reacted with Merrifield resin to afford an immobilized cyclooctadiene in high yield. This polymer is effective as a halogen scavenger, while hydroboration leads to a supported 9-BBN analogue. The latter exhibits similar regioselectivity to 9-BBN in olefin hydroboration. [reaction: see text]