Journal of the American Chemical Society

Two-photon chemistry in the laser jet: photoionization of the diphenylmethyl radical generated by Norrish type I photocleavage of benzhydryl phenyl ketone

W Adam, RS Oestrich

文献索引：Adam, Waldemar; Oestrich, Rolf Schulte Journal of the American Chemical Society, 1992 , vol. 114, # 15 p. 6031 - 6034

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被引用次数: 13

摘要

Abstract: It is shown that in the laser jet (LJ) mode (argon ion laser) the benzhydryl phenyl ketone (1) undergoes a twephoton reaction in CCl, to yield benzhydryl chloride. The one- photon products are 1, 1, 2, 2-tetraphenylethane (3), benzophenone, and 1, l, l-trichloro-2, 2- diphenylethane (4). In methanol, on the other hand, our results suggest even a three-photon reaction in which benzhydryl methyl ether (5) is produced besides the one-photon ...