Tetrahedron

Selective and efficient alcoholyses of allylic, secondary-and tertiary benzylic alcohols in the presence of iron (III)

P Salehi, N Iranpoor, FK Behbahani

文献索引：Salehi, Peyman; Iranpoor, Nasser; Behbahani, Farahnaz Kargar Tetrahedron, 1998 , vol. 54, # 5-6 p. 943 - 948

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被引用次数: 80

摘要

An efficient and selective method for the conversion of allylic, secondary-and tertiary benzylic alcohols into their corresponding ethers in the presence of iron (III) as FeCl3 and Fe (ClO4) 3 under solvolytic condition is described. The results obtained from an optically active allylic alcohol show that a carbonium ion is formed during the course of the reaction.