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Kinetics and Mechanism of Reactions of Benzhydryl Chlorides with Anilines

S Chang, HJ Koh, BS Lee, I Lee

文献索引:Chang, Saemin; Koh, Han Joong; Lee, Bon-Su; Lee, Ikchoon Journal of Organic Chemistry, 1995 , vol. 60, # 24 p. 7760 - 7768

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被引用次数: 19

摘要

Nucleophilic substitution reactions of substituted benzhydryl chlorides with anilines in acetonitrile and methanol are investigated. The reactions are found to proceed by the attack of nucleophile on the preformed carbocation, I, within the ion pair. The cross-interaction ...