Carbene in a rigid matrix. XII. Temperature and substituent effects on regioselectivity in the insertion of arylcarbene into alcohols

H Tomioka, S Suzuki, Y Izawa

文献索引：Tomioka, Hideo; Suzuki, Shinji; Izawa, Yasuji Journal of the American Chemical Society, 1982 , vol. 104, # 11 p. 3156 - 3162

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被引用次数: 18

摘要

Abstract: Photolysis of aryldiazomethanes in methanol, ethanol, and 2-propanol gave OH insertion products along with small amounts of CH insertion products at ambient temperature. However, the CH insertion products increased significantly at the expense of the ether as the temperature was lowered. The attempted sensitized decomposition of the diazomethane did not lead to an increase in the CH insertion products presumably ...