Effects of Phosphorus Substituents on Reactions of α??Alkoxyphosphonium Salts with Nucleophiles

A Goto, K Otake, O Kubo, Y Sawama…

文献索引：Goto, Akihiro; Otake, Kazuki; Kubo, Ozora; Sawama, Yoshinari; Maegawa, Tomohiro; Fujioka, Hiromichi Chemistry - A European Journal, 2012 , vol. 18, # 36 p. 11423 - 11432

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被引用次数: 6

摘要

Abstract The effects of phosphorus substituents on the reactivity of α-alkoxyphosphonium salts with nucleophiles has been explored. Reactions of α-alkoxyphosphonium salts, prepared from various acetals and tris (o-tolyl) phosphine, with a variety of nucleophiles proceeded efficiently. These processes represent the first examples of high-yielding nucleophilic substitution reactions of α-alkoxyphosphonium salts. The reactivity of these ...