Radical ions in photochemistry. Part 24. Carbon-carbon bond cleavage of radical cations in solution: theory and application

R Popielarz, DR Arnold

文献索引：Popielarz; Arnold Journal of the American Chemical Society, 1990 , vol. 112, # 8 p. 3068 - 3082

被引用次数: 155

摘要

Abstract: The cleavage of radical cations of two series of alkanes, 1, 1, 2-triaryl-and 1, 1, 2, 2- tetraaryIalkanes, generated by photoinduced single electron transfer in acetonitrile- methanol, occurs with formation of radical and carbocation fragments. The radical cations of some unsymmetrically substituted alkanes cleave to give all four of the possible products, two hydrocarbons emanating from the radicals and two methyl ethers from the ...

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~91%

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~46%

~86%

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