Journal of the Chinese Chemical Society

Tandem thermal reactions for the synthesis of jasmonoids

TL Ho, KF Shyu

文献索引：Ho, Tse-Lok; Shyu, Kuo-Feng Journal of the Chinese Chemical Society, 1998 , vol. 45, # 2 p. 319 - 321

被引用次数: 0

摘要

Abstract A tandem reaction tactic for the preparation of a jasmonoid intermediate consists of pyrolysis of a spiroannulated cyclopentanone. The thermal decomposition actually involves a retro-Diels-Alder reaction and a homo-1, 5-hydrogen shift with cleavage of the cyclopropane unit.

~74%

~60%

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