Tetrahedron letters

Synthesis of 2-substituted 1, 3-butadienyl compounds by palladium-catalyzed regioselective 1, 2-elimination reaction of methylvinylcarbinol acetates

A Carpita, F Bonaccorsi, R Rossi

文献索引：Carpita, Adriano; Bonaccorsi, Fabrizio; Rossi, Renzo Tetrahedron Letters, 1984 , vol. 25, # 45 p. 5193 - 5196

全文：HTML全文

被引用次数: 17

摘要

Abstract Alkylation of the dianion of 3-methyl-3-buten-2-ol, followed by acetylation and palladium-catalyzed 1, 2-elimination reaction of the so obtained methylvinylcarbinol acetates allows to synthesize regioselectively 2-substituted 1, 3-butadienyl compounds having high isomeric purity.