Chemistry Letters

A practical synthesis of myrcenol by palladium complex-catalyzed elimination reaction

H Kumobayashi, S Mitsuhashi, S Akutagawa…

文献索引：Kumobayashi, Hidenori; Mitsuhashi, Shigeru; Akutagawa, Susumu; Ohtsuka, Sei Chemistry Letters, 1986 , p. 157 - 160

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被引用次数: 22

摘要

A Palladium complex-catalyzed elimination reaction of allyl amines was studied to establish a practical process for production of myrcenol. The catalytic elimination occurred smoothly with the cationic Pd (II) complexes. Among a variety phosphorous ligands, the tetramethylene and the pentamethylene diphosphine ligands proved to be the best ligand with respects to the catalytic activity and selectivity.