Vapor generation of inorganic anionic species after aqueous phase alkylation with trialkyloxonium tetrafluoroborates

A D'Ulivo, E Pagliano, M Onor, E Pitzalis…

文献索引：D'Ulivo, Alessandro; Pagliano, Enea; Onor, Massimo; Pitzalis, Emanuela; Zamboni, Roberto Analytical Chemistry, 2009 , vol. 81, # 15 p. 6399 - 6406

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被引用次数: 23

摘要

Aqueous phase reaction of trialkyloxonium tetrafluoroborates, R3O+ BF4−(R Me, Et) has been tested in the alkylation of simple inorganic anionic substrates such as halogen ions, cyanide, thiocyanate, sulphide and several oxoanions or their corresponding oxoacids. Gaseous products were separated and identified by gas chromatography mass spectrometry (GC-MS). Alkylated derivatives RI, RBr, RCl were obtained for iodide, bromide, and ...