Tetrahedron

Carbon-halogen bond activation by nickel catalyst: Synthesis of alkenes, from 1, 2-dihalides

C Malanga, S Mannucci, L Lardicci

文献索引：Malanga, Corrado; Mannucci, Serena; Lardicci, Luciano Tetrahedron, 1998 , vol. 54, # 7 p. 1021 - 1028

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被引用次数: 21

摘要

Unsaturated hydrocarbons can easily be prepared in a few seconds starting from 1, 2 dibromides in the presence of a catalytic amount of Nickel diphenylphosphinoethane dichloride (NidppeCl2) and tri. n. butyl tin hydride,(TBTH) at room temperature. The dependencie of the nature of starting dihalides is investigated.