Tetrahedron letters

Cobalt (II)-porphyrin catalyzed selective functionalization of alkanes with sulfurylchloride: A remarkable substituent effect

V Khanna, P Tamilselvan, SJS Kalra, J Iqbal

文献索引：Khanna, Vibha; Tamilselvan, Pitchiah; Kalra, Swinder Jeet Singh; Iqbal, Javed Tetrahedron Letters, 1994 , vol. 35, # 32 p. 5935 - 5938

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被引用次数: 7

摘要

Abstract Cobalt (II)-porphyrin complex 1 and 2 catalyses the chlorination and sulfochlorination respectively of n-alkanes and cycloalkanes with sulfuryl chloride in benzene. The p-substituent of the benzene ring in the porphyrin complex 1 and 2 shows a remarkable chemoselectivity in these reactions.