Gas-Phase Ion-Molecular Reactions of Free Ethylsilylium Ions with Ethylene

…, TA Kochina, EN Sinotova, IS Ignat'ev

文献索引：Shchukin; Kochina; Sinotova; Ignat'ev Russian Journal of General Chemistry, 2001 , vol. 71, # 2 p. 206 - 209

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被引用次数: 3

摘要

Abstract Gas-phase reaction of ethylsilylium ions with ethylene was studied by the radiochemical method. The reaction occurs via excited adduct C 4 H 11 Si+ which structurally is a complex of ethylsilylium cation with ethylene. The lifetime of this complex is long enough for the isotope exchange between tritium atoms of the cation and a proton of ethylene, as well as the isomerization of ethylsilylium cation to dimethylsilylium to occur. ...