From carbon dioxide to methane: Homogeneous reduction of carbon dioxide with hydrosilanes catalyzed by zirconium-borane complexes

T Matsuo, H Kawaguchi

文献索引：Matsuo, Tsukasa; Kawaguchi, Hiroyuki Journal of the American Chemical Society, 2006 , vol. 128, # 38 p. 12362 - 12363

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被引用次数: 126

摘要

Carbon dioxide is the stable carbon end product of metabolism and other combustions, and it is an abundant yet low-value carbon source. This molecule would be very valuable as a renewable source if it were to be effectively transformed into reduced organic compounds under mild conditions. 1 However, thermodynamic stability of CO 2 has prevented its utilization in industrial chemical processes, and thus this represents a continuing scientific challenge. Here we ...