Gas-phase reactions of iron (1-) and cobalt (1-) with simple thiols, sulfides, and disulfides by Fourier-transform mass spectrometry

L Sallans, KR Lane, BS Freiser

文献索引：Sallans, L.; Lane, K. R.; Freiser, B. S. Journal of the American Chemical Society, 1989 , vol. 111, # 3 p. 865 - 873

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被引用次数: 33

摘要

Abstract: Fe-and Co-are found to react with simple thiols, sulfides, and disulfides. The primary reaction products formed from these metal anions, M-, and thiols include MS-, MSH-, and MSHC and suggest a mechanism involving initial insertion of the metal into the weak CS bond. Similarly, CS insertion is the main mode of attack in the reactions with the sulfides and disulfides, in analogy to what is observed for the reaction of metal cations. Collision- ...