Chemical Communications

A novel palladium-catalyzed coupling of epoxides with allyl bromide mediated by indium (i) chloride: a cascade epoxide rearrangement–carbonyl allylation

N Jiang, Q Hu, CS Reid, Y Lu, CJ Li

文献索引：Jiang, Nan; Hu, Qingyuan; Reid, Carrolyn S.; Lu, Yunfeng; Li, Chao-Jun Chemical Communications, 2003 , # 18 p. 2318 - 2319

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被引用次数: 1

摘要

Allylation of aldehydes is an important transformation in organic synthesis. 1 Over the past decade, allylation reactions by allylic indium reagents, in particular, have been of increasing interest because of their tolerance to water, which allows their wide uses in aqueous media for environmentally benign syntheses. 2 Generally, the allylindium reagent can be prepared by the conventional transmetalation of allyllithium or allyl Grignard reagents with indium(III) ...