Palladium-catalyzed carbonyl allylation by allylic alcohols with stannous chloride

JP Takahara, Y Masuyama…

文献索引：Takahara, Jun P.; Masuyama, Yoshiro; Kurusu, Yasuhiko Journal of the American Chemical Society, 1992 , vol. 114, # 7 p. 2577 - 2586

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被引用次数: 196

摘要

Abstract: Allylic alcohols can be applied to carbonyl allylation via the formation of r- allylpalladium complexes, using palladium as catalyst and SnC1, as a reducing agent. This reaction has chemoselectivity: The reactivity order of allylating agents is allylic carbonate> allylic alcohol> allylic acetate, and that of carbonyl compounds is aldehyde> ketone. High regioselection was observed in polar solvents such as DMF, DMI, and DMSO; carbonyl ...