A fine-tuned molybdenum hexacarbonyl/phenol initiator for alkyne metathesis

V Sashuk, J Ignatowska, K Grela

文献索引：Sashuk, Volodymyr; Ignatowska, Jolanta; Grela, Karol Journal of Organic Chemistry, 2004 , vol. 69, # 22 p. 7748 - 7751

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被引用次数: 57

摘要

A new, highly potent activator for molybdenum hexacarbonyl and 2-fluorophenol is described. An “instant” catalyst formed in situ from molybdenum hexacarbonyl and 2- fluorophenol shows high activity for cross-and ring-closing alkyne metathesis reaction. The use of 2-fluorophenol can be combined with other activation methods to allow alkyne metathesis at relatively low temperature (80° C).